Topic Plan of Practical Lessons on Physical Chemistry

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Topic Plan of Practical Lessons on Physical Chemistry
Module I
For the 2-nd Year Foreign Students of the Pharmaceutical Faculty
Pharmaceutical Chemistry Department
2010-2011, Semester IV
speciality «Clinical Рharmacy» 7.110206
№
Hours
1.
2
Behavior of Gases. Ideal-Gas Law. Fundamental concepts of chemical thermodynamics.
2.
2
Heat. Work. The first law of thermodynamics. Thermochemistry.
3.
2
The second and third laws of thermodynamics.
4.
2
Criteria of the equilibrium and the driving force or spontaneity of the process.
2
Constant of the chemical equilibrium. Calculate of the reactants and products
concentrations in the equilibrium mixture.
2
The effect of pressure and temperature on the equilibrium. Le Chatelier’s Principle.
Chemical reaction isotherm. Dependence of Equilibrium Constant on temperature.
Isochor and Isobar of chemical reaction.
Thermodynamics of phase equilibria. Phase rule for a one-component and binary systems.
Methods of physical-chemical analysis.
Extraction. Partition equilibrium. Laboratory Experiment “Determination of the partition
coefficient of a substance between the two immiscible solvents”.
Phase diagrams of binary solutions. Azeotropes.
5.
6.
7.
2
8.
2
9.
2
10.
2
11.
2
2
12.
13.
2
Topic
Quantitative ways of expressing concentration: molarity (M), molality (m), parts by mass,
parts by volume, mole fraction. Solutions ionic strength. Activity.
Colligative Properties of Solutions.
Laboratory Experiment «Determination of an isotonic coefficient, dissociation degree,
electrolyte dissociation constant and molar mass of a substance by measuring the boiling
point of a solution”.
Comprehensive chek module 1.
Conductivity of Solutions. Conductometry method.
2
Electrode Potentials. Galvanic Cells. Laboratory Experiment «Potentiometric
determination of electrolyte concentration».
15.
2
16.
2
Electrolysis.
Comprehensive chek module 2.
Rate of chemical reaction. Rate law. Order of reaction.
17.
2
Factors affecting rates of reactions. Determination of Drugs Expiry Date.
2
Laboratory Experiment «Determination of basic kinetic parameters of hydrolysis
saccharose».
Comprehensive chek module 3.
14.
18.
19.
2
2
Concluding session for the Module 1. Physical Chemistry
Computer testing.
Concluding session for the Module 1. Physical Chemistry
20.
Calculation problems.

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