The Zebron

Document technical information

Format pdf
Size 5.4 MB
First found Nov 13, 2015

Document content analysis

Language
English
Type
not defined
Concepts
no text concepts found

Organizations

Places

Transcript

™
GC Columns
Guaranteed, Drop-In Performance for Chlorinated Pesticides
ZB-CLPesticides-1 & -2
•Direct replacement for Restek® Rtx®-CLPesticides column pair
•7 EPA methods, one column set
•Reduce downtime – run multiple methods without changing columns
The Zebron
“Do More With Less”
Everyday Low List Price
Instantly Save On
Every Column & Kit, Every Time
www.phenomenex.com/PesticidesGC
Introducing the Zebron™ Experience
Get More Than Just A Column
When you choose Zebron, you get more than just high quality
GC products. Choosing Zebron means you get access to a wide
variety of tools, resources, and personalized support to help make
your GC work easier, faster, and simply better.
Our Customers
Come First
“
Phenomenex has always given superb
customer support. I changed suppliers from…
Agilent to Phenomenex based on your
customer support…about 10 years ago and
you have not failed me since that point !
“
Marie Coschigano
Genzyme Corp. USA
Continued Innovation
Our inventive GC scientists have 25+ years of experience, and many helped create keystone phases at J&W Scientific
before joining the Phenomenex team. Zebron’s track record of innovation is the only to be recognized with 3 R&D 100
Awards and 2 Readers’ Choice awards!
ZB-WAXPLUS™
100 % water stable
Birth of Zebron GC
Columns
1998
2004
MS Phases
2
2005
Inferno™ Phases
Stable up to 430 °C
2006
2007
ZB-MultiResidue™ Phases
Targeted selectivity for
pesticide screening
© 2014 Phenomenex, Inc. All rights reserved.
ZB-1XT SimDist
Robust simulated distillation
2009
ZB-Drug-1
For drugs of abuse
ZB-Bioethanol
5 min results
2010
ZB-CLPesticides Phases
Versatility for pesticides by
GC/ECD
2012
2014
ZB-SemiVolatiles
Supreme inertness for
SVOCs, PBDEs, and PAHs
ZB-CLPesticides-1 & -2
™
A Drop-In Alternative for Pesticide Testing by GC/ECD
GC Columns
p.4 Do More With Less
Run 7 EPA Methods On One Column Set
Save On Every Column & Kit with Everyday Low List Pricing
6 Get All of the Benefits with None of the Risk
Choose A Direct Replacement for Restek® Rtx®-CLPesticides Phases
Guaranteed Performance With Quality by Design
8 See the Zebron vs. Restek Comparison Tests
EPA 8081: Chlorinated Pesticides
EPA 8082: Polychlorinated Biphenyls (PCBs)
EPA 8151: Chlorinated Herbicides
EPA 504: EDB, DBCP, and TCP
EPA 505: Organohalide Pesticides
EPA 508: Chlorinated Pesticides, Herbicides, and Organohalides
EPA 552: Haloacetic Acids (HAAs) and Dalapon
17 Trust Real-World Results: Customer Spotlight
18 Get More Than Just A Column
Meet Your Pesticide Support Team
Access Free Resources 24/7
Keep in Calibration with Phenova® CRMs
Explore the Pesticide Column Family
23 Ordering Information
If Zebron columns do not provide you with equivalent
or better separations as compared to any other GC
column of the same phase and comparable dimensions, return the column with comparative data within
45 days for a FULL REFUND.
Phenomenex
l WEB: www.phenomenex.com
3
Do More With Less
Run 7 EPA Methods On One Column Set
Zebron™ ZB-CLPesticides-1 and -2 allow you to run multiple methods without changing columns for faster,
easier pesticide analysis. Save time and gain flexibility – run multiple pesticide classes on one instrument,
on one column pair.
•
•
Resolve multiple pesticide classes with enhanced, fine-tuned selectivity
Meet dual-column requirements for 7 EPA methods by GC/ECD
8081: Chlorinated Pesticides
8082: Polychlorinated Biphenyls (PCBs)
8151: Chlorinated Herbicides
504: EDB, DBCP, and TCP
505: Organohalide Pesticides
508: Chlorinated Pesticides, Herbicides, and Organohalides
552: Haloacetic Acids (HAAs) and Dalapon
Wouldn’t You Rather Be On Vacation?
The time and money you save when you choose
ZB-CLPesticides columns allows you to invest your
resources elsewhere. Increase your lab’s
productivity and take a well-deserved break!
Learn more at
www.phenomenex.com/VacationCLP
4
Phenomenex
l WEB: www.phenomenex.com
™
GC Columns
Instantly Save On Every Column & Kit
Today’s pesticide testing labs are pushed to deliver more precise results with less resources. Switching to
ZB-CLPesticides columns you get robust, reliable performance – and you save money too! Our “Do More
With Less” everyday low list pricing saves you money on every column and kit you purchase.
Make the
Switch and
SAVE!
Zebron
ZB-CLPesticides
Columns
.
S
V
Restek®
Rtx®-CLPesticides
Columns
Want to Know How Much You Save?
Contact your GC specialist to see your everyday low
list price. You may even qualify for extra savings with
special offers! Learn more at
www.phenomenex.com/PesticidesGC
Phenomenex
l WEB: www.phenomenex.com
5
All of the Benefit, None of the Risk
Direct Replacement for Restek Rtx -CLPesticides Phases
®
®
You asked for optimized performance for pesticides by GC/ECD detectors, without time-consuming method
development. We’ve delivered a direct replacement*! ZB-CLPesticides-1 and -2 provide guaranteed drop-in
performance compared to your current Rtx-CLPesticides column set, without the hassle.
Zebron
Restek®
TM
.
S
V
Drop-In Results: Real Customer Data, Real Performance
ZB-CLPesticides-1
“
ZB-CLPesticides-2
I was able to install the
ZB-CLPesticides-1 and
ZB-CLPesticides-2 columns as a direct
replacement for the Restek RtxCLPesticides and Rtx-CLPesticides2
columns that I currently use. I made
no changes to the method and
saw very little difference between
the two columns.
“
Joanne Foy, Chemist
TriMatrix Laboratories, Inc.
Ready To See The Method
Comparison Tests?
Go to page 8
* Direct Replacement: this category indicates an alternative column which will likely give a similar selectivity.
6
Phenomenex
l WEB: www.phenomenex.com
™
GC Columns
Guaranteed Performance With Quality by Design
Choosing ZB-CLPesticides-1 and -2 means you get accurate, reproducible results with guaranteed performance
and dramatic cost savings from Phenomenex. Our GC R&D and manufacturing team has on average 25+ years of
experience – this expertise means you get products designed to work out-of-the-box, headache free.
• Stringent individual QC testing – no batch tests
• Aggressive test mixes that check for efficiency, bleed, activity, and retention characteristics
• Excellent sensitivity and reproducibility
• Good stability and long column lifetimes
Our 100 % Risk-Free Guarantee
If Zebron columns do not provide you with
equivalent or better separations as compared
to any other GC column of the same phase
and comparable dimensions, return the column with comparative data within 45 days for
a FULL REFUND.
Phenomenex
l WEB: www.phenomenex.com
7
EPA 8081
Chlorinated Pesticides by GC/ECD
Drop-In Method Performance
ZB-CLPesticides columns combine Zebron™ high quality with drop-in selectivity. Achieve near-exact elution profiles
and run times, without the time-consuming method development and headaches typical of traditional selectivities!
Conditions for all columns:
Columns: As listed
Dimensions: As listed
Part Number: 7HM-G028-51 (ZB-CLPesticides-1)
7HM-G029-11 (ZB-CLPesticides-2)
Injection: Splitless (hold 0.3 min) @ 250 °C, 1 µL
Carrier Gas: Helium @ 3.9 mL/min (constant flow)
Oven Program: 120 °C to 200 °C @ 45 °C/min to 230 °C @ 15 °C/min
to 330 °C @ 30 °C/min for 2 min
Detector: ECD @ 330 °C
Y-Connector: AG0-4717 (Borosilicate Glass)
Guard Column: 7AM-G000-00-GZ0 (5 m Z-Guard™)
Liner: AG0-8499 (Single Taper with Wool at Bottom)
Septum: AG0-4696 (PhenoRed™-400)
Inlet Seal: AG0-8620 (Gold-Plated Easy Seal™)
Reference Standards: See page 21.
Sample: Analytes are 250 ng/mL in hexane.
Equivalent Elution Profile
Why pay more when you can drop in
a direct replacement for less?
Zebron
See p. 9 for analytes
ZB-CLPesticides-1
ZB-CLPesticides-2
30 m x 0.32 mm x 0.32 µm
22632
30 m x 0.32 mm x 0.25 µm
2
2
3
5
5
3
6
7
8
1
6
21
13
9
10 12
17
14 16
11
15
21
7
12
8 9 10
11
1
22
19
13
15 16
14
19
18
18
20
3
4
4
APP ID 22631
4
2
22
17
5
6
7
min
APP ID 22632
22631
20
2
3
4
5
6
7
min
Restek
®
Rtx®-CLPesticides
Rtx-CLPesticides2
30 m x 0.32 mm x 0.32 µm
30 m x 0.32 mm x 0.25 µm
22634
22633
2
3
2
5
3
6
5
7
8
1
9 1012
11
21
13
17
6
22
14
15 16
7
1
19
8
12 13
9 10
11
21
141516 17
19
22
18
APP ID 22633
4
20
2
3
4
5
6
7
Conditions for each method were the same for all columns tested.
Comparative separations are not representative of all applications.
8
Phenomenex
l WEB: www.phenomenex.com
min
APP ID 22634
18
4
20
2
3
4
5
6
7
min
™
GC Columns
Easily Meet EPA Specifications
The EPA outlines strict performance requirements for compound linearity, percent relative standard deviation
(% RSD), and breakdown of DDT and Endrin. The ZB-CLPesticides column pair meets these guidelines, providing
accurate data well-suited for your analysis.
0
Peak Area
50
100
150
200
Concentration (ng/mL)
250
40000
40000
40000
30000
30000
30000
0
50
50
50
Heptachlor Epoxide R22= 0.9995
Heptachlor
Epoxide
R = 0.9999
Heptachlor
R2 = 0.9989
Heptachlor R2 = 0.9993
100
150
200
2 250
=250
0.9987 300
Dieldrin
R
100
150
200
300
Concentration (ng/mL)
DDT R2 = 0.9979
Concentration (ng/mL)
Endrin R2 = 0.9990
100
150
200
Concentration (ng/mL)
250
50
50
50
HeptachlorDieldrin
Epoxide
0.9999
0.9987
R2R2=2 =
Dieldrin
R0.9993
= 0.9992
Heptachlor
DDT RR22=2=
0.9979
DDT
R
0.9976
Endrin 2 2= 0.9990
100
150
200
250
Endrin R =
0.9997 300
100Concentration
150 (ng/mL)
200
250
300
100
150
200
250
300
Concentration (ng/mL)
Concentration (ng/mL)
30000
Dieldrin R2 = 0.9992
DDT R2 = 0.9976
Endrin R2 = 0.9997
0
50
100
150
200
Concentration (ng/mL)
2
10000
250
3.8
3.0
2
Heptachlor Epoxide
8.3 R = 0.9999
Heptachlor R2 = 0.9993
a-BHC
100
150
200 5.9
Concentration (ng/mL)
250
300
US EPA
Specifications
< 20
3.8
< 20
5.6
< 20
4
b-BHC
6.9
6.9
< 20
5
d-BHC
4.9
5.7
< 20
6
Heptachlor
8.0
6.5
< 20
40000
7
40000
30000
Aldrin
4.2
2.3
< 20
20000
8
30000
10000
90
20000
Heptachlor epoxide
3.8
2.3
< 20
10
10000
0
0
trans-Chlordane
50
100
Heptachlor Epoxide R2 = 0.9999
Heptachlor
R2 = 0.9993
4.1
150
200
250
Dieldrin R = 0.9992
cis-ChlordaneConcentration (ng/mL)
4.0
DDT R2 = 0.9976
4,4'-DDE
50
Endosulfan
Dieldrin
2
300
Endrin R2 = 0.9997
4.8
100
150
200
I Concentration (ng/mL) 6.0
250
300
7.7
3.8
< 20
3.3
< 20
2.9
< 20
2.5
< 20
4.9
< 20
40000
Endrin
9.4
6.6
< 20
30000
15
4,4'-DDD
9.2
3.6
< 20
16
Endosulfan II
6.6
4.1
< 20
17
4,4'-DDT
6.9
< 20
200 8.3
7.3
< 20
14
20000
10000
180 0 Endrin
50 aldehyde
100
Dieldrin R2 = 0.9992
DDT
R2 = 0.9976
11.6
Endrin R2 = 0.9997
150
250
300
19
Concentration (ng/mL)
Endosulfan sulfate
8.0
7.1
< 20
20
Methoxychlor
6.7
6.1
< 20
21
Endrin ketone
6.5
7.2
< 20
22
Decachlorobiphenyl (Surr)
6.7
6.6
< 20
Average
6.6%
4.9%
* Calculated as response factors as per EPA guidelines
20000
0
2,4,5,6-TCMX (Surr)
1
20000
13
ZB-CLPesticides-2
10000
30000
12
ZB-CLPesticides-1
20000
20000
20000
10000
10000
10000
0
Analyte
110
300
ZB-CLPesticides-1 ZB-CLPesticides-2
% RSD*
% RSD*
No.
40000
30 0 g-BHC
50
300
ZB-CLPesticides-2
40000
40000
40000
30000
30000
20000
30000
20000
10000
10000
20000
0
00
0
10000
40000
300
Peak Area
10000
Peak Area
Peak Area
PeakPeak
Area
Peak
Area
Area
Peak
Area
Peak
Area
Peak
Area
Heptachlor Epoxide R2 = 0.9995
Heptachlor R2 = 0.9989
0
0
00
0
300
.9987
9979
9990
0
20000
0
0.9995
0.9987
989
9979
09990 300
0
30000
0
300
Peak
40000
Peak Area
Peak Area
ZB-CLPesticides-1
0.9995
989
0
Five-Point Calibration Curve at 5, 15, 25, 100, and 250 ng/mL
< 20
300
Tech Tip: Minimize Activity
Inlet deactivation is critical for obtaining stable
calibration curves. Use a well-deactivated liner
and remember to change your gold seal regularly
when working with Agilent® 5890, 6890, and 7890
instruments.
Phenomenex
l WEB: www.phenomenex.com
9
EPA Method 8082
Polychlorinated Biphenyls (PCBs)
Conditions for all columns:
Columns: As listed
Dimensions: As listed
Part Number: 7HM-G028-51 (ZB-CLPesticides-1)
7HM-G029-11 (ZB-CLPesticides-2)
Injection: Pulsed Splitless @ 30 psi (hold 20 sec) @ 250 °C, 1 µL
Carrier Gas: Helium @ 60 cm/sec (constant flow)
Oven Program: 120 °C to 200 °C @ 45 °C/min to 330 °C @
15 °C/min for 2 min
Detector: ECD @ 330 °C
Y-Connector: AG0-4717 (Borosilicate Glass)
Guard Column: 7AM-G000-00-GZ0 (5 m Z-Guard™)
Liner: AG0-8499 (Single Taper with Wool at Bottom)
Septum: AG0-4696 (PhenoRed™-400)
Inlet Seal: AG0-8620 (Gold-Plated Easy Seal™)
Reference Standards: See page 21.
Sample: Aroclor is 1000 ng/mL and SS and IS are 100 ng/mL in hexane.
1. Tetrachloro-meta-xylene (TCMX)*
2. Decachlorobiphenyl**
* surrogate standard
Would you
** internal standard
Download the full PCB application note and see
comparisons for all 7 aroclors in EPA 8082 online!
Need Detailed Congener Resolution?
Zebron ZB-MultiResidue™ columns provide
enhanced separations in under 30 minutes.
Learn more at
www.phenomenex.com/PesticidesGC
pay more for your reflection’s clothes?
No! With drop-in performance, making the smart choice to save with Zebron is simple.
Learn how you can do more with less on p. 5.
Zebron
TM
ZB-CLPesticides-1
ZB-CLPesticides-2
Aroclor 1260
30 m x 0.32 mm x 0.32 µm
22642
Compare All the PCB Aroclors
1
2
2
2
4
6
8
APP ID 22649
APP ID 22642
1
Aroclor 1260
30 m x 0.32 mm x 0.25 µm
22649
2
10 min
4
6
8
10 min
Restek
®
Rtx®-CLPesticides
Rtx-CLPesticides2
Aroclor 1260
30 m x 0.32 mm x 0.32 µm
Aroclor 1260
30 m x 0.32 mm x 0.25 µm
22658
22657
2
2
4
6
8
Conditions for each method were the same for all columns tested.
Comparative separations are not representative of all applications.
10
Phenomenex
l WEB: www.phenomenex.com
10 min
APP ID 22658
APP ID 22657
1
2
4
6
8
10 min
EPA Method 8151
Chlorinated Herbicides
Sample: Analytes are 100 ng/mL in hexane.
Conditions for all columns:
1. Dalapon methyl ester
Columns: As listed
2. 3,5-Dichlorobenzoic acid methyl ester*
Dimensions: As listed
3. 4-Nitroanisole
Part Number: 7HM-G028-51 (ZB-CLPesticides-1)
4. DCAA methyl ester*
7HM-G029-11 (ZB-CLPesticides-2)
5. Dicamba methyl ester
Injection: Splitless (hold 0.75 min) @ 250 °C, 1 µL
6. MCPP methyl ester
Carrier Gas: Helium @ 36 cm/sec (constant flow)
7. MCPA methyl ester
Oven Program: 70 °C for 0.5 min to 190 °C @ 25 °C/min for
8. Dichlorprop, methyl ester
1 min to 300 °C @ 11 °C/min for 5 min
9. 4,4’-DBOB**
Detector: ECD @ 325 °C
10. 2,4-D methyl ester
Y-Connector: AG0-4717 (Borosilicate Glass)
Guard Column: 7AM-G000-00-GZ0 (5 m Z-Guard™)
Liner: AG0-8499 (Single Taper with Wool at Bottom)
Septum: AG0-4696 (PhenoRed™-400)
Inlet Seal: AG0-8620 (Gold-Plated Easy Seal™)
With drop-in, guaranteed performance,
Reference Standards: See page 21.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
Pentachloroanisole
2,4,5-TP methyl ester
2,4,5-T methyl ester
Chloramben methyl ester
2,4-DB methyl ester
Dinoseb methyl ester
Bentazon methyl ester
DCPA methyl ester (Chlorthal-dimethyl)
Pichloram methyl ester
Acifluorfen methyl ester
* surrogate standard
** internal standard
at a lower price, the ZB-CLPesticides pair is
better than:
a. Sliced Bread
b. Rainbows and Unicorns
c. @%$#!
Answer: all of the above! Our customers said so. See more of their thoughts on p. 17.
Zebron
TM
ZB-CLPesticides-1
ZB-CLPesticides-2
30 m x 0.32 mm x 0.32 µm
30 m x 0.32 mm x 0.25 µm
22620
22619
11
11
9
2
1
4
3 4
17,19
13
14
67
20
16
8 10
15
6
8
10
12
18
APP ID 22619
18
12
5
14 min
12
5
2
1
2
3
4
7
6
4
8
6
19
13
14
20
16
10
15
8
17
10
12
APP ID 22620
9
14 min
Restek
®
Rtx®-CLPesticides
Rtx-CLPesticides2
30 m x 0.32 mm x 0.32 µm
30 m x 0.32 mm x 0.25 µm
22630
22629
11
11
9
9
18
17,19
20
18
14
16
2
34
1
4
6
67
8
10
15
8
10
12
14 min
12
19
20
APP ID 22630
5
13
APP ID 22629
12
13
14
5
16
2
3
1
4
6
4
6 7
8
10
15
8
17
10
12
14 min
Conditions for each method were the same for all columns tested.
Comparative separations are not representative of all applications.
Phenomenex
l WEB: www.phenomenex.com
11
EPA Method 504
EDB, DBCP, and TCP
Conditions for all columns:
Columns: As listed
Dimensions: As listed
Part Number: 7HM-G028-51 (ZB-CLPesticides-1)
7HM-G029-11 (ZB-CLPesticides-2)
Injection: Pulsed Splitless @ 25 psi (hold 0.5 min) @ 200 °C, 2 µL
Carrier Gas: Helium @ 60 cm/sec (constant flow)
Oven Program: 30 °C for 2 min to 200 °C @ 30 °C/min
Detector: ECD @ 220 °C
Y-Connector: AG0-4717 (Borosilicate Glass)
Guard Column: 7AM-G000-00-GZ0 (5 m Z-Guard™)
Liner: AG0-8499 (Single Taper with Wool at Bottom)
Septum: AG0-4696 (PhenoRed™-400)
Inlet Seal: AG0-8620 (Gold-Plated Easy Seal™)
Zebron
TM
ZB-CLPesticides-1
22623
Sample:
Analytes are 250 ng/mL in hexane.
1. Bromodichloromethane
2. Chlorodibromomethane
3. 1,2-Dibromomethane (EDB)
4. 1,1,1,2-Tetrachloroethane
5. Bromoform
6. 1,2,3-Trichloropropane
7. 1,2-Dibromo-3-chloropropane (DBCP)
Reference Standards: See page 21.
Don’t Rely On Magic To Save You Money
Trust guaranteed performance. Try ZB-CLPesticides columns and get the same results
you’re used to, risk-free. Learn more on p. 7.
ZB-CLPesticides-2
22624
30 m x 0.32 mm x 0.32 µm
30 m x 0.32 mm x 0.25 µm
4
4
1
2
2
7
7
3
6
2
3
4
5
6
min
APP ID 22624
APP ID 22623
1
5
5
3
6
2
3
4
5
6
min
22626
Restek
Rtx®-CLPesticides
30 m x 0.32 mm x 0.32 µm
Rtx-CLPesticides2
30 m x 0.32 mm x 0.25 µm
4
4
2
2
1
6
3
4
5
6 min
7
5
APP ID 22625
3
2
1
7
APP ID 22626
5
3
6
2
3
4
5
Tech Tip: Improve Signal-to-Noise
Conditions for each method were the same for all columns tested.
Comparative separations are not representative of all applications.
12
Phenomenex
l WEB: www.phenomenex.com
Proper column conditioning reduces unnecessary
column bleed and improves your analysis. For
best results, be sure to condition your Zebron
column at max isothermal temperature until a
constant baseline is achieved.
6
min
EPA Method 505
Organohalide Pesticides
Conditions for all columns:
Columns: As listed
Dimensions: As listed
Part Number: 7HM-G028-51 (ZB-CLPesticides-1)
7HM-G029-11 (ZB-CLPesticides-2)
Injection: Splitless (hold 0.75 min) @ 250 °C, 2 µL
Carrier Gas: Helium @ 40 cm/sec (constant flow)
Oven Program: 90 °C for 1 min to 310 °C @ 10 °C/min for 5 min
Detector: ECD @ 325 °C
Y-Connector: AG0-4717 (Borosilicate Glass)
Guard Column: 7AM-G000-00-GZ0 (5 m Z-Guard™)
Liner: AG0-8499 (Single Taper with Wool at Bottom)
Septum: AG0-4696 (PhenoRed™-400)
Inlet Seal: AG0-8620 (Gold-Plated Easy Seal™)
Sample:
Analytes are 200 ng/mL in ethanol except atrazine and simazine at 4.2 µg/mL.
1. Hexachlorocyclopentadiene
9. Heptachlor Epoxide
2. Hexachlorobenzene
10. γ-Chlordane
3. Simazine
11. trans-Nonachlor
4. Atrazine
12. α-Chlordane
5. γ-BHC
13. Dieldrin
6. Heptachlor
14. Endrin
7. Alachlor
15. cis-Nonachlor
8. Aldrin
16. Methoxychlor
Reference Standards: See page 21.
Zebron
TM
ZB-CLPesticides-1
ZB-CLPesticides-1
30 m x 0.32 mm x 0.32 µm
ZB-CLPesticides-2
30 m x 0.32 mm x 0.25 µm
22621
22622
11,12
5
8
2
6
8
9 1011
12 13
6
2
9 10
13
15
14
1
6
APP ID 22621
14
16
7
3
8
10
12
14
15
16
18
20
min
1
3,4
16
7
6
8
10
12
14
16
18
20
APP ID 22622
4,5
min
Restek
Rtx®-CLPesticides
Rtx-CLPesticides2
30 m x 0.32 mm x 0.32 µm
30 m x 0.32 mm x 0.25 µm
22628
22627
2
11,12
5
5
2
8
6
10
13
7,8
15
6
9
9
10
11
12
13
15
14
16
1
4
3
6
8
10
7
12
14
16
18
20
min
1
APP ID 22628
APP ID 22627
14
16
4
3
6
8
10
12
14
16
18
20
min
Looking For Love In Aldrin Places?
Start a cheap romance with Zebron ZB-CLPesticides columns. Their elution orders and
run times are consistent, so they show up on time for dates. And they bring flowers and
chocolates, too.
Conditions for each method were the same for all columns tested.
Comparative separations are not representative of all applications.
Phenomenex
l WEB: www.phenomenex.com
13
EPA Method 508
Chlorinated Pesticides, Herbicides,
& Organohalides
Zebron
TM
ZB-CLPesticides-1
Conditions for all columns:
Columns: As listed
Dimensions: As listed
Part Number: 7HM-G028-51 (ZB-CLPesticides-1)
7HM-G029-11 (ZB-CLPesticides-2)
Injection: Splitless (hold 0.75 min) @ 250 °C, 2 µL
Carrier Gas: Helium @ 26 cm/sec (constant flow)
Oven Program: 80 °C for 0.5 to 155 °C @ 19 °C/min for 1 min to
210 °C @ 4 °C/min to 310 °C @ 25 °C/min for 10 min
Detector: ECD @ 325 °C
Y-Connector: AG0-4717 (Borosilicate Glass)
Guard Column: 7AM-G000-00-GZ0 (5 m Z-Guard™)
Liner: AG0-8499 (Single Taper with Wool at Bottom)
Septum: AG0-4696 (PhenoRed™-400)
Inlet Seal: AG0-8620 (Gold-Plated Easy Seal™)
Reference Standards: See page 21.
Sample: Analytes are various concentrations in ethyl acetate.
30 m x 0.32 mm x 0.32 µm
22635
24,25
20,21,22 26,27
6
19
28 31
29
15
7,4
11
10,12 13
2
16 14
18
36
23
17
8
10
14
16
37 38
30
8 9
12
See p. 15 for analytes
34
5
3
35
APP ID 22635
1
6
32
33
18
20
22
24
26
min
ZB-CLPesticides Columns Are Tastier Than DDT!
That doesn’t make any sense, but saving money does. Why pay more when you
get equivalent or better results with Zebron?
Restek
Rtx-CLPesticides
30 m x 0.32 mm x 0.32 µm
22637
25
6
19
21
1
26,27
28
7
11 10
13
15
14
16
34
18
36
20,22
5
12
3
6
8
4
10
12
24
23
17
8 9
14
16
18
Conditions for each method were the same for all columns tested.
Comparative separations are not representative of all applications.
14
Phenomenex
35
APP ID 22637
2
33
3132
29
l WEB: www.phenomenex.com
20
30
22
37 38
24
26
min
™
GC Columns
Zebron
TM
Peak
No. Analyte
ZB-CLPesticides-2
30 m x 0.32 mm x 0.25 µm
22636
25
19,21
15
27 28
18
16
13 14
7
2
29
17
12
6
8
10
12
16
24
36
30
8,9
14
35
34
23
5
4
31 32
33
11
10
1
3
22 26
37 38
20
18
20
22
24
26
APP ID 22636
6
min
Restek
Rtx-CLPesticides2
30 m x 0.32 mm x 0.25 µm
22638
25
19,20
21
27
28
1
26
22
15
11
10
8
10
12
13
14
29
100
Trifluralin
100
Hexachlorobenzene
100
α-BHC
50
Simazine
100
Atrazine
100
Pentachloronitrobenzene **
50
γ-BHC
50
β-BHC
50
δ-BHC
50
Heptachlor
50
Chlorothalonil
100
Metribuzin
100
Alachlor
100
Aldrin
50
4,4'-Dibromobiphenyl*
250
Metachlor
100
DCPA(dacthal)
100
Heptachlor epoxide (isomer B)
50
trans-Chlordane
100
Cyanazine
cis-Chlordane
Endosulfan I
4,4′-DDE
100
100
50
50
Dieldrin
50
Chlorobenzilate
100
Endrin
4,4′-DDD
Endosulfan II
4,4′-DDT
Endrin aldehyde
50
50
50
50
50
Endosulfan sulfate
50
cis-Permethrin
100
Methoxychlor
trans-Permethrin
50
100
35
34
16 18
36
37
17
89
14
100
Propachlor
24
12
6
100
Chloroneb
31 33
32
5
4
100
Etridiazole
APP ID 22638
7
3
Concentration
(ng/mL)
Hexachlorocyclopentadiene
* surrogate standard
** internal standard
6
2
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
31.
32.
33.
34.
35.
36.
37.
38.
30
16
18
20
22
24
38
Keep In Calibration!
26 min
Improve your pesticide analysis and
throughput with Phenova® Certified
Reference Materials.
Learn more on page 20
Conditions for each method were the same for all columns tested.
Comparative separations are not representative of all applications.
Phenomenex
l WEB: www.phenomenex.com
15
EPA Method 552
Haloacetic Acids (HAAs) and Dalapon
Peak
No.
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
Conditions for all columns:
Columns: As listed
Dimensions: As listed
Part Number: 7HM-G028-51 (ZB-CLPesticides-1)
7HM-G029-11 (ZB-CLPesticides-2)
Injection: Pulsed Splitless @ 25 psi (hold 0.75 min) @ 250 °C,
1 µL
Carrier Gas: Helium @ 25 cm/sec (constant flow)
Oven Program: 35 °C for 4 min to 250 °C @ 15 °C/min, hold 5 min
Detector: ECD @ 300 °C
Y-Connector: AG0-4717 (Borosilicate Glass)
Guard Column: 7AM-G000-00-GZ0 (5 m Z-Guard™)
Liner: AG0-8499 (Single Taper with Wool at Bottom)
Septum: AG0-4696 (PhenoRed™-400)
Inlet Seal: AG0-8620 (Gold-Plated Easy Seal™)
Reference Standards: See page 21.
Sample: Analytes are various concentrations in ethyl acetate.
Concentration
(ng/mL)
1500
1000
1500
1000
500
4000
1000
1000
500
2500
2000
5000
Analyte
Methyl chloroacetate
Methyl bromoacetate
Methyl dichloroacetate
Dalapon methyl ester
Methyl trichloroacetate
1,2,3-Trichloropropane**
Methyl bromochloroacetate
Methyl bromodichloroacetate
Methyl dibromoacetate
Methyl chlorodibromoacetate
2,3 dibromopropionate*
Methyl tribromoacetate
* surrogate standard
** internal standard
Wow, These Chromatograms Look The Same
Good thing they do – they’re supposed to! Performance is headache and hassle-free,
so you can drop-in and run with minimal method development – and pay less!
Zebron
TM
ZB-CLPesticides-1
ZB-CLPesticides-2
30 m x 0.32 mm x 0.32 µm
30 m x 0.32 mm x 0.25 µm
22669-
12
12
10
10
11
11
7
9
5
3
APP ID 22668
7
2
4
6
1
6
10
8
12
14
min
8
9
5
3
APP ID 22669
8
2
4
6
1
8
10
12
14
min
Restek
®
Rtx®-CLPesticides
Rtx-CLPesticides2
30 m x 0.32 mm x 0.32 µm
30 m x 0.32 mm x 0.25 µm
22671
22623
12
12
10
10
11
11
2
4
6
1
8
10
12
14
Conditions for each method were the same for all columns tested.
Comparative separations are not representative of all applications.
16
Phenomenex
l WEB: www.phenomenex.com
min
8
9
5
3
APP ID 22671
APP ID 22670
9
5
3
7
8
7
2
4
6
1
8
10
12
14
min
Customer Spotlight
Real-World Results with Zebron™ ZB-CLPesticides
Run Faster Methods With Minimal Development Time
We installed Zebron ZB-CLPesticides-1 and -2 columns with our current method and did
no further optimization. Overall, the Zebron columns are fairly impressive. ZB-CLPesticides
columns are comparable to our current columns, with the added benefit of no co-eluting
peaks. There is also the potential to optimize our method parameters using these columns
to run a slightly faster analysis.
Shealy Environmental
Services, Inc.
Equivalent Elution Orders & Calibration Success
“I tried the Zebron ZB-CLPesticides column pair and compared them to the
Restek® Rtx®-CLPesticides and Rtx-CLPesticides2 columns. The elution of
the Aroclor 1016/1260 standards looked very similar to the Restek columns.
I ran a five point curve for the 1016/1260 Aroclors and single points for the
rest of the Aroclors (1221 through 1268). The % RSD for the 1016/1260
peaks were also very similar to the Restek column results.”
TriMatrix Laboratories, Inc.
Share With Us!
Our innovation is fueled by your feedback! We
take every opportunity to learn about your
GC challenges, how your dream column would
perform, and how best to support you.
www.phenomenex.com/WeListen
Phenomenex
l WEB: www.phenomenex.com
17
Meet Your Pesticide Support Team
Your Personal GC Specialist
Let us put you first. Your GC technical consultant is available to provide unlimited, personalized support to
help you solve your unique GC challenges. From troubleshooting support to liner selection, we’re committed
to getting your questions answered, fast and friendly!
Our Lab Is Your Lab
PhenoLogix is our full-service analytical support laboratory. Let our GC gurus save your lab time and money!
• Application development services
• Method optimization and development support
• GC column screening and recommendations
• On-site method development
• On-site, hands-on training
www.phenomenex.com/PhenoLogix
18
Free Pesticide Resources 24/7
Explore Online Tips & Tools
You asked for a better online experience. One filled with technical resources, easy-to-find products, and
useful tools to make your pesticide work easier. Good news… it’s here!
• Get thousands of applications – save and access them anywhere!
• Watch technical demonstrations and “how-to” videos
• Create a virtual stockroom for your lab
• Try tools that make selecting the right product easier than ever
• Get FREE samples and special offers
www.phenomenex.com/PesticidesGC
Request A FREE GC Accessory Sample
Need inlet liners, septa, or gold seals for your
pesticide work? Try a sample on us!
www.phenomenex.com/PesticidesGC
Available in USA and Canada.
Soon to arrive in regions around
the globe!
19
Improve Pesticide Analysis & Throughput
with Phenova Certified Reference Materials
®
Keeping You in Calibration
Phenova CRMs provide lot-to-lot consistency by analytically verifying with internal and external CRMs. This
means you will experience minimal trending and fewer out of control calibrations.
• Take control
• Extend your calibration window
• Improve your sample throughput
Consistent Quality
Using ISO/IEC 17025 and ISO Guide 34 compliant quality programs, Phenova CRMs are manufactured and
analytically verified, promising you consistency and accuracy each time.
• Get accurate results
• Improve your data quality and analysis
A New Standard of Confidence
Phenova CRMs are manufactured by Phenova, Inc. (Golden, Colorado, USA), a
Phenomenex Company, which is accredited to ISO Guide 34:2009, and
ISO/IEC 17025:2005
AC C R EDITED
ChemicalTesting
Testing Laboratory
Chemical
Laboratory
Certificate No. 2427.03
Certificate No. 2427.03
AC C RE D I TE D
Proficiency Testing Provider
Reference
Material
Producer
Certificate
No. 2427.01
Reference
Material
Producer
Certificate
No. 2427.02
Certificate No. 2427.02
Who Needs to Use
Certified Reference Materials?
All environmental labs accredited to ISO/IEC 17025 must use CRMs. Even if your
lab does not have this accreditation it still benefits from having a high standard,
quality product.
20
Discover A New Standard of Confidence
• Extended calibration
• High quality and confidence
• Dependable inventory
• Simple and smart packaging
• Personalized technical support
• Streamlined product search
• ...and more
Make the Switch to Reliability and Convenience
Part No.
Product Name
Description
Calibration
Standard
Internal
Standard
AL0-101253
8081 Chlorinated Pesticides
1000 µg/mL in Hexane/Toluene
✓
AL0-101254
Chlorinated Pesticides Standard
2000 µg/mL in Hexane/Toluene
✓
AL0-101258
Toxaphene
2000 µg/mL in Methanol
✓
AL0-101260
Technical Chlordane
1000 µg/mL in Methanol
✓
AL0-101255
8141 OP Pesticides
200 µg/mL in Hexane/Acetone (90:10)
✓
AL0-101256
8270 OP Pesticides Mix
2000 µg/mL in Methylene Chloride
✓
AL0-101290
Pentachloronitrobenzene
100 µg/mL in Ethyl Acetate
AL0-101259
4,4'-Dibromobiphenyl
500 µg/mL in Ethyl Acetate
AL0-101267
Pentachloronitrobenzene
5000 µg/mL in Acetone
✓
AL0-101268
1-Bromo-2-nitrobenzene
5000 µg/mL in Acetone
✓
AL0-101269
1-Bromo-2-nitrobenzene
1000 µg/mL in Acetone
✓
AL0-101272
4-Chloro-3-Nitrobenzotrifluoride
1000 µg/mL in Acetone
✓
AL0-101257
Pesticide Surrogate Mix
500 µg/mL in Acetone
AL0-101263
2,4,5,6-Tetrachloro-m-xylene
200 µg/mL in Acetone
AL0-101274
Decacholorobiphenyl Standard
200 µg/mL in Acetone
AL0-101288
Chlorinated Acid Herbicides
100 µg/mL in Acetonitrile
✓
AL0-101289
MCPP & MCPA
20000 µg/mL in Acetonitrile
✓
AL0-101265
Simazine
1000 µg/mL in Acetone
✓
AL0-101271
Atrazine
1000 µg/mL in Acetone
✓
AL0-101266
Triazine Herbicides Mix
200 µg/mL in Acetone
✓
AL0-101270
4,4’-Dibromooctofluorobiphenyl
250 µg/mL in Hexane
AL0-101261
2,4-Dichlorophenylacetic Acid
1000 µg/mL in Acetone
Available in the USA and Canada.
Soon to arrive in regions around the globe!
Surrogate
Standard
Price
✓
✓
✓
✓
✓
✓
✓
✓
✓
✓
We’re Here to Help!
For a full selection of Phenova CRMs and analyte
listing by EPA Method visit
www.phenomenex.com/Standards
[email protected]
21
A Full-Solutions Family for Pesticide Testing
The Choice Is Yours
Though many pesticide methods are standardized, every lab is different! We know that today’s labs test for
an increasingly diverse list of methods and compounds. The Zebron™ pesticide column family is up to the
challenge.
ZB-CLPesticides-1 & -2
ZB-MultiResidue -1 & -2
TM
7 Chlorinated Pesticides Methods On One Set
Optimized Selectivity, Enhanced Separations
• Guaranteed results for 7 EPA methods by GC/ECD
• Drop-in performance equivalent to Restek®
Rtx®-CLPesticides phases
• Reliably detect to low levels on-column
• Sensitive, accurate results for GC/ECD and GC/MS
ZB-SemiVolatiles
Guaranteed Alternatives
Supreme Inertness for Tough Pesticide Samples
Traditional Selectivities With A Twist
• Good peak shapes and response at trace levels for active pesticide compounds
• No retention time shifts from other 5 % phenyl arylene phases
• Improve your separations, without time-consuming
method development
• ZB-XLB, ZB-35, ZB-1701P and other direct replacements
available
Free Column Selection Guide!
Download your free GC Selection Companion and
get the details on the pesticide column family.
www.phenomenex.com/PesticidesGC
22
Ordering Information
ZB-CLPesticides GC Columns
ZB-CLPesticides-1 GC Columns
Length (m)
30
ID (mm)
0.25
0.32
0.32
0.53
df (µm)
0.25
0.32
0.50
0.50
Temperature Limits (°C)
Restek Part No.
Temperature Limits (°C)
Restek Part No.
40 to 320/340
40 to 320/340
40 to 320/340
40 to 320/340
11123
11141
11139
11140
Part No.
Price
Part No.
Price
7HG-G028-11
7HM-G028-51
7HM-G028-17
7HK-G028-17
ZB-CLPesticides-2 GC Columns
Length (m)
30
ID (mm)
0.25
0.32
0.32
0.53
df (µm)
0.20
0.25
0.50
0.42
40 to 320/340
40 to 320/340
40 to 320/340
40 to 320/340
11323
11324
11325
11340
ZB-CLPesticides GC Column Kits
ZB-CLPesticides 0.25 mm ID Kit
Part No.: KG0-9285
Price: $880
Dimension
Restek Part No.
11123
11323
10026
20403-261
--
7HG-G028-11
7HG-G029-10
7AG-G000-00-GZ0
AG0-4717
AG0-5722
Part No.: KG0-9286
Price: $920
Restek Part No.: 11196
Dimension
30 meter x 0.32 mm x 0.32 µm
30 meter x 0.32 mm x 0.25 µm
5 meter x 0.32 mm
Universal Borosilicate Glass
0.5 mL, rated to 350 °C
Restek Part No.
11123
11323
10027
20403-261
--
Part No.
7HM-G028-51
7HM-G029-11
7AM-G000-00-GZ0
AG0-4717
AG0-5722
Part No.: KG0-9290
Price: $1,015
Restek Part No.: 11197
Dimension
30 meter x 0.53 mm x 0.50 µm
30 meter x 0.53 mm x 0.42 µm
5 meter x 0.53 mm
Universal Borosilicate Glass
0.5 mL, rated to 350 °C
Restek Part No.
11140
11340
10045
20403-261
--
Part No.
7HK-G028-17
7HK-G029-16
7AK-G000-00-GZ0
AG0-4717
AG0-5722
Includes 1 of Each Below
Description
ZB-CLPesticides-1
ZB-CLPesticides-2
Z-Guard™ Column
Y-Connector
Polyimide Resin
ZB-CLPesticides 0.32 mm ID Kit
Includes 1 of Each Below
Description
ZB-CLPesticides-1
ZB-CLPesticides-2
Z-Guard Column
Y-Connector
Polyimide Resin
ZB-CLPesticides 0.53 mm ID Kit
Includes 1 of Each Below
Description
ZB-CLPesticides-1
ZB-CLPesticides-2
Z-Guard Column
Y-Connector
Polyimide Resin
7HG-G029-10
7HM-G029-11
7HM-G029-17
7HK-G029-16
30 meter x 0.25 mm x 0.25 µm
30 meter x 0.25 mm x 0.20 µm
5 meter x 0.25 mm
Universal Borosilicate Glass
0.5 mL, rated to 350 °C
Recommended Accessories
Restek Part No.: 11199
Part No.
Price
Price
If Zebron columns do not
provide you with equivalent or
better separations as compared
to any other GC column of the
same phase and comparable
dimensions, return the column
with comparative data within 45
days for a FULL REFUND.
Price
Liners for Agilent Technologies® (HP) GC Systems (GC Model No. 5880/5890/6890/7890)
Description
Benefits / Uses
Dimensions
ID x L x OD (mm)
Units
Similar to Mfr. No.**
Part No.
Unit
–
AG0-4680
AG0-7514
5/pk
25/pk
AG0-8499
AG0-9170
5/pk
25/pk
21054
21055
20998
–
AG0-7850
–
5/pk
5183-4647
5183-4701
5183-4702
21032
21033
–
–
AG0-8172
–
5/pk
5181-3316
5183-4695
5183-4696
20798
20799
20780
–
AG0-7516
AG0-7640
5/pk
25/pk
Split / Splitless, FocusLiner™ Single Taper
with wool
General use or dirty samples
4 x 78.5 x 6.3
ea
5/pk
25/pk
5183-4711
5183-4712
5183-4713
Splitless, Single Taper Liner with wool
Large injection, trace analysis
4 x 78.5 x 6.3
5/pk
25/pk
5183-4693
5183-4694
Single Taper Direct Connect with Side Hole (top)
Great recovery and linearity
for trace analysis of active
compounds
4 x 78.5 x 6.3
ea
5/pk
25/pk
G1544
Split Liner with wool
General use or dirty samples
4 x 78.5 x 6.3
ea
5/pk
25/pk
Splitless Single Taper Liner
Large injection, trace analysis
4 x 78.5 x 6.45
ea
5/pk
25/pk
Phenomenex
20994
20995
20996
Price
l WEB: www.phenomenex.com
23
™
GC Columns
Guaranteed, Drop-In Performance for Chlorinated Pesticides
ZB-CLPesticides-1 & -2
Australia
t: 02-9428-6444
f: 02-9428-6445
[email protected]
Austria
t: 0
1-319-1301
f: 01-319-1300
[email protected]
Belgium
Luxembourg
t: +31 (0)30-2418700
f: +31 (0)30-2383749
[email protected]
Mexico
t: 001-800-844-5226
f: 001-310-328-7768
[email protected]
The Netherlands
t: 02 503 4015 (French)
t: 02 511 8666 (Dutch)
f: +31 (0)30-2383749
t: 030-2418700
f: 030-2383749
Canada
t: (800) 543-3681
f: (310) 328-7768
[email protected]
t: 09-4780951
f: 09-4780952
Denmark
t: 4824 8048
f: +45 4810 6265
[email protected]
t: 8
10 02 005
f: +45 4810 6265
Finland
t: 09 4789 0063
f: +45 4810 6265
[email protected]
t: ( 800) 541-HPLC
f: ( 310) 328-7768
France
t: 01 30 09 21 10
f: 01 30 09 21 11
[email protected]
t: 08 611 6950
f: +45 4810 6265
Germany
t: 06021-58830-0
f: 06021-58830-11
[email protected]
t: 0
1625-501367
f: 0
1625-501796
India
t: 040-3012 2400
f: 040-3012 2411
[email protected]
t: (310) 212-0555
f: (310) 328-7768
[email protected]
Ireland
t: 01 247 5405
f: +44 1625-501796
[email protected]
[email protected]
New Zealand
[email protected]
Norway
[email protected]
Puerto Rico
[email protected]
Sweden
[email protected]
United Kingdom
[email protected]
United States
[email protected]
All other countries:
Corporate Office USA
t: (310) 212-0555
f: (310) 328-7768
[email protected]
Italy
t: 0
51 6327511
f: 0
51 6327555
[email protected]
www.phenomenex.com
Phenomenex products are available worldwide. For the distributor in your country,
contact Phenomenex USA, International Department at [email protected]
Terms and Conditions
Subject to Phenomenex Standard Terms and Conditions, which may be viewed at
www.phenomenex.com/TermsAndConditions.
BR22260414_W
Trademarks
Easy Seals, Guardian, MultiResidue, PhenoRed, Z-Guard, Inferno, WAXPLUS and Zebron
are trademarks of Phenomenex. Restek and Rtx are registered trademarks of Restek
Corporation. FocusLiner is a trademark of SGE. Agilent and Agilent Technologies are
registered trademarks of Agilent Technologies, Inc.
Disclaimer
Phenomenex is not affiliated with Restek Corporation or Agilent Technologies, Inc.
Comparative separations may not be representative of all applications.
The opinions stated herein are solely those of the speaker and not necessarily those of
any company or organization.
© 2014 Phenomenex, Inc. All rights reserved.

Similar documents

×

Report this document